-361 kJ/mol heat would be released if 2 moles of nitrogen and 2 moles of oxygen form 4 moles of NO (g) at 101.3 kPa and 298 K.
Enthalpy of formation is defined as the heat change that is needed for formation of one mole of a substance from its constituent elements in pure state.
In the present case, Heat of formation of 4 moles of NO (g) at 101.3 kpa and 298 k is -90.25 kJ/mol. The Negative sign indicates that, heat is evolved from the system.
Thus, for 4 moles of NO, the heat of formation will be 4 X (-90.25 kJ/mol) = -361 kJ/mol.
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