Respuesta :
Answer:
2.45×10^54
Explanation:
Mg(s) + Zn2+(aq) = Mg2+(aq) + Zn(s)
From the equation;
n= 2 moles of electrons
E°anode= -2.37 V
E°cathode= -0.76 V
From E°Cell= E°cathode - E°anode
E°Cell= -0.76-(-2.37) = 1.61 V
Recall that E°cell= 0.0592/n log K
1.61= 0.0592/2 log K
log K = 1.61/0.0296
K= Antilog (54.39)
K= 2.45×10^54
To determine the equilibrium constant for the above chemical reaction is [tex]2.51 \times 10^{54}[/tex]
Given the following data:
- Temperature = 25°C
The balanced chemical equation for the reaction is:
[tex]Mg{(s)} + Zn^{2+} {(aq)} = Mg^{2+} (aq) + Zn(s)[/tex]
- Number of moles of electrons = 2 moles
- The standard reduction potential for anode, [tex]E^\circ (Anode) = -2.372[/tex]
- The standard reduction potential for cathode, [tex]E^\circ (Cathode) = -0.7618[/tex]
To determine the equilibrium constant for the above chemical reaction:
Mathematically, the standard cell potential of a galvanic cell is given by the formula:
[tex]E^\circ_{cell}= E^\circ (Anode) -E^\circ (Anode)\\\\E^\circ_{cell}= -0.7618-(-2.372)\\\\E^\circ_{cell}= -0.7618+2.372\\\\E^\circ_{cell}=1.6102\; Volt[/tex]
Now, we can determine the equilibrium constant by using the formula:
[tex]E_{cell}^\circ = \frac{0.0592}{n} logK[/tex]
Substituting the parameters into the formula, we have;
[tex]1.6102 = \frac{0.0592}{2} logK\\\\1.6102 =0.0296logK\\\\logK = \frac{1.6102}{0.0296} \\\\logK =54.40\\\\K = log^{-1}(54.40)\\\\K = 2.51 \times 10^{54}[/tex]
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