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0.030 moles of a weak acid, HA, was dissolved in 2.0 L of water to form a solution. At equilibrium, the concentration of HA was found to be 0.013 M. Determine the value of Ka for the weak acid.

Respuesta :

Answer: The value of [tex]k_{a}[/tex] for the weak acid is [tex]3.07 \times 10^{-4}[/tex].

Explanation:

First, we will calculate the molarity of HA as follows.

     [HA] = [tex]\frac{\text{no. of moles}}{\text{volume}}[/tex]

             = [tex]\frac{0.03 mol}{2 L}[/tex]

             = 0.015

At equilibrium,

              [tex]HA + H_{2}O \rightleftharpoons H_{3}O^{+} + A^{-}[/tex]

Initial:   0.015                  0          0

Change:  -x                     +x         +x

Equilibm: 0.015 - x          x           x

It is given that, at equilibrium

          [HA] = 0.015 - x = 0.013

             - x = 0.013 - 0.015

                  = 0.002

Now, expression for [tex]k_{a}[/tex] of this reaction is as follows.

          [tex]k_{a} = \frac{[A^{-}][H_{3}O^{+}]}{[HA]}[/tex]

                      = [tex]\frac{x^{2}}{[HA]}[/tex]

                      = [tex]\frac{(0.002)^{2}}{0.013}[/tex]

                      = [tex]3.07 \times 10^{-4}[/tex]

Thus, we can conclude that the value of [tex]k_{a}[/tex] for the weak acid is [tex]3.07 \times 10^{-4}[/tex].

The value of Ka for the weak acid should be 3.07*10^-4 when 0.030 moles of a weak acid.

Calculation of the value of Ka:

First determine the molarity of HA

= 0.03 mol / 2L

= 0.015

Now

HA = 0.015 -x = 0.013

-x = 0.013 - 0.015

= 0.002

Now the value should be

= (0.002)^2/0.013

= 3.07*10^-4

Hence, The value of Ka for the weak acid should be 3.07*10^-4 when 0.030 moles of a weak acid.

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